Anne of Green Gables is wonderful. :) I haven't read the books in years, but I loved them. As for the movies/show, the only ones I've seen are Anne of Green Gables and Anne of Avonlea -- with Megan Follows as Anne. I'll have to reread the books. The Emily of New Moon books, also by LMM, were beautiful, too.

Han/Leia were awesome, too. I don't love them enough for them to be on this list, but they were great fun.